CUET UG Physics Booster Test 3- Bohr Model Postulates
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QUESTION 1 OF 20
Which is an incorrect statement about the conflict between classical theory and atomic stability?
QUESTION 2 OF 20
If classical theory held true and an electron's energy decreased continuously, its velocity v and radius r would mathematically change such that the ratio (v² × r) would be proportional to:
QUESTION 3 OF 20
Choose the correct statements regarding the inward spiral trajectory (Classical):
1. The centripetal force is provided by the electrostatic attraction.
2. Radiation causes total energy E to become increasingly negative.
3. The radius of the orbit gradually approaches infinity.
4. It contradicts the experimental observation of stable matter.
QUESTION 4 OF 20
The collapse of the classical Rutherford atom is inevitable because:
QUESTION 5 OF 20
Choose the correct statements concerning the frequency emitted by a classical collapsing atom:
1. The emitted frequency matches the electron's mechanical frequency of revolution.
2. Since the electron's angular velocity increases as it spirals inward, the emitted frequency increases continuously.
3. The result would be a continuous emission spectrum containing all possible wavelengths up to a limit.
4. This theoretical continuous spectrum perfectly explained the glow tube emissions of rarefied gases.
QUESTION 6 OF 20
Match List I with List II (Observation/Theory)
| List I | List II |
|---|---|
| 1. Condensed matter radiation | a. Continuous distribution of wavelengths |
| 2. Rarefied gases in a flame | b. Discrete wavelengths (line spectrum) |
| 3. Classical accelerating electron | c. Continuous frequency change during spiral |
| 4. Bohr model transitions | d. Frequency defined by ΔE/h |
QUESTION 7 OF 20
The fundamental contrast between Rutherford's orbits and Bohr's orbits is that Rutherford's are radiatively _______, while Bohr's are radiatively _______.
QUESTION 8 OF 20
The concept of "stationary states" in Bohr's model:
QUESTION 9 OF 20
According to de Broglie's explanation of Bohr's second postulate, an electron moving in the 3rd orbit (n = 3) forms a standing wave. If the de Broglie wavelength is λ, the circumference of this orbit is:
QUESTION 10 OF 20
Which is an incorrect statement regarding the quantisation rule and de Broglie's explanation?
QUESTION 11 OF 20
During a transition from state n = 3 to n = 2, the energy of the emitted photon in a hydrogen atom is:
QUESTION 12 OF 20
In Bohr's model, the frequency of the emitted photon during a transition:
QUESTION 13 OF 20
The absorption spectrum of a material:
1. shows bright lines on a dark background.
2. contains dark lines corresponding to frequencies where photons have exactly the energy needed to excite an electron.
3. is independent of the atom's energy states.
4. forms a completely continuous dark band.
Choose correct:
QUESTION 14 OF 20
Choose the correct statements related to energy, frequency and transitions:
1. Ei − Ef = hν applies for emission.
2. Ei + hν = Ef applies for absorption, where nf > ni.
3. Bohr's model can accurately predict the relative intensities of the emitted frequencies.
4. Atomic energies are often expressed in electron volts rather than joules.
QUESTION 15 OF 20
Choose the correct statements about the quantised orbit radius:
1. The radius is proportional to the square of the principal quantum number.
2. The smallest possible radius corresponds to n = 1.
3. The spacing between successive orbits (rₙ₊₁ − rₙ) is constant.
4. The radius expression includes the mass of the electron in the denominator.
QUESTION 16 OF 20
If the Bohr radius a₀ = 5.3 × 10⁻¹¹ m, what is the radius of the second excited state of a hydrogen atom?
QUESTION 17 OF 20
Match List I (Energy expressions in Bohr orbit) with List II (Dependencies in terms of constants)
| List I | List II |
|---|---|
| 1. Total Energy E | a. −e²/(8πε₀r) |
| 2. Potential Energy U | b. −e²/(4πε₀r) |
| 3. Kinetic Energy K | c. e²/(8πε₀r) |
| 4. Radius r | d. ε₀h²n²/(πme²) |
QUESTION 18 OF 20
As the principal quantum number n increases, the absolute value of energy becomes _______, and the total energy E becomes progressively _______.
QUESTION 19 OF 20
The ground state of a hydrogen atom is defined such that:
QUESTION 20 OF 20
Which is an incorrect statement regarding the higher energy states (excited states)?
Test Complete!
Answer Review
1 Which is an incorrect statement about the conflict between classical theory and atomic stability?
�� Classical theory fails for atomic systems. �� It cannot explain atomic stability. �� It cannot explain line spectra.
Classical mechanics and classical electromagnetic theory successfully explain many macroscopic phenomena, but they fail to explain atomic stability and discrete atomic spectra. This failure led to the development of quantum theory. Therefore, option D is correct.
- �� Option A → Correct statement.
- �� Option B → Circular motion implies centripetal acceleration.
- �� Option C → Energy loss causes shrinking orbit and changing frequency.
Used
- Concept Validation
Application:
- Identify the statement inconsistent with experimental observations.
Final Logic:
- Classical theory alone cannot explain atomic structure.
Classical Works Big, Fails Small
2 If classical theory held true and an electron's energy decreased continuously, its velocity v and radius r would mathematically change such that the ratio (v² × r) would be proportional to:
�� Electrostatic force provides centripetal force. �� Equate Coulomb force and centripetal force. �� Rearrangement gives v²r relation.
For a hydrogen atom, mv²/r = e²/(4πε₀r²) Multiplying both sides by r²: mv²r = e²/(4πε₀) Therefore, v²r = e²/(4πε₀m) Hence option A is correct.
- �� Options B, C and D do not follow from the force balance equation.
Used
- Formula Application
Application:
- Use Coulomb force = centripetal force.
Final Logic:
- v²r = e²/(4πε₀m)
v²r = Coulomb Constant Part
3 Choose the correct statements regarding the inward spiral trajectory (Classical):
1. The centripetal force is provided by the electrostatic attraction.
2. Radiation causes total energy E to become increasingly negative.
3. The radius of the orbit gradually approaches infinity.
4. It contradicts the experimental observation of stable matter.
�� Electrostatic attraction provides centripetal force. �� Energy loss shrinks the orbit. �� Stable matter contradicts classical prediction.
Statement 1 is correct because Coulomb attraction provides the centripetal force. Statement 2 is correct because continuous radiation decreases total energy. Statement 3 is incorrect because the orbit shrinks toward the nucleus, not infinity. Statement 4 is correct because atoms are experimentally stable. Therefore, statements (1), (2) and (4) are correct.
- �� All other options include statement 3, which is false.
Used
- Statement Verification
Application:
- Evaluate each statement individually.
Final Logic:
- Orbit radius decreases, not increases.
Energy Loss → Smaller Orbit
4 The collapse of the classical Rutherford atom is inevitable because:
�� Accelerating charge emits radiation. �� Electron loses energy continuously. �� Orbit collapses inward.
According to classical electromagnetic theory, every accelerating charge radiates energy. Since an orbiting electron is continuously accelerated, it must radiate energy, lose orbital energy, and spiral into the nucleus. Therefore, option B is correct.
- �� Option A → Not the reason for collapse.
- �� Option C → Atomic binding is electrostatic.
- �� Option D → No such absorption process occurs.
Used
- Cause-Effect Analysis
Application:
- Identify the fundamental reason for instability.
Final Logic:
- Radiation by accelerating charge causes collapse.
Acceleration → Radiation → Collapse
5 Choose the correct statements concerning the frequency emitted by a classical collapsing atom:
1. The emitted frequency matches the electron's mechanical frequency of revolution.
2. Since the electron's angular velocity increases as it spirals inward, the emitted frequency increases continuously.
3. The result would be a continuous emission spectrum containing all possible wavelengths up to a limit.
4. This theoretical continuous spectrum perfectly explained the glow tube emissions of rarefied gases.
�� Classical theory links emitted frequency to revolution frequency. �� Orbit shrinks continuously. �� Continuous spectrum is predicted.
Statements 1, 2 and 3 follow directly from classical theory. Statement 4 is incorrect because rarefied gases experimentally show line spectra, not continuous spectra. Therefore, option A is correct.
- �� All other options contain statement 4.
Used
- Theory vs Observation
Application:
- Compare classical prediction with experiments.
Final Logic:
- Classical theory predicts continuous spectra.
Continuous Orbit → Continuous Spectrum
6 Match List I with List II (Observation/Theory)
| List I | List II |
|---|---|
| 1. Condensed matter radiation | a. Continuous distribution of wavelengths |
| 2. Rarefied gases in a flame | b. Discrete wavelengths (line spectrum) |
| 3. Classical accelerating electron | c. Continuous frequency change during spiral |
| 4. Bohr model transitions | d. Frequency defined by ΔE/h |
�� Condensed matter → continuous spectrum. �� Rarefied gases → line spectrum. �� Classical spiral → continuously changing frequency. �� Bohr → ΔE/h.
List I — List II 1. Condensed matter radiation — a. Continuous distribution of wavelengths 2. Rarefied gases in a flame — b. Discrete wavelengths (line spectrum) 3. Classical accelerating electron — c. Continuous frequency change during spiral 4. Bohr model transitions — d. Frequency defined by ΔE/h Thus, option A is correct.
- �� They contain incorrect pairings.
Used
- Direct Matching
Application:
- Match concepts with defining properties.
Final Logic:
- Only option A satisfies all pairings.
Condensed → Continuous, Gas → Lines
7 The fundamental contrast between Rutherford's orbits and Bohr's orbits is that Rutherford's are radiatively _______, while Bohr's are radiatively _______.
�� Rutherford orbits radiate. �� Bohr stationary orbits do not. �� Stability is restored in Bohr's model.
Rutherford's model predicts continuous radiation and instability. Bohr introduced stationary non-radiating orbits, making atoms stable. Therefore, option B is correct.
- �� They contradict the basic difference between the two models.
Used
- Comparison
Application:
- Compare orbital behavior.
Final Logic:
- Rutherford unstable, Bohr stable.
Rutherford Radiates, Bohr Behaves
8 The concept of "stationary states" in Bohr's model:
�� Electron keeps moving. �� No radiation occurs. �� Energy remains fixed.
A stationary state does not mean the electron is motionless. It means the electron moves in an allowed orbit without emitting radiation and retains a definite energy. Therefore, option B is correct.
- �� Option A → Electron is not at rest.
- �� Option C → No continuous absorption required.
- �� Option D → Incorrect interpretation.
Used
- Definition Recall
Application:
- Recall Bohr's first postulate.
Final Logic:
- Stationary state = constant energy orbit.
Stationary Energy, Not Stationary Electron
9 According to de Broglie's explanation of Bohr's second postulate, an electron moving in the 3rd orbit (n = 3) forms a standing wave. If the de Broglie wavelength is λ, the circumference of this orbit is:
�� Standing wave condition: 2πr = nλ �� For n = 3: 2πr = 3λ
According to de Broglie: 2πrn = nλ For n = 3, 2πr = 3λ Hence the circumference equals 3λ. Therefore, option C is correct.
- �� They do not satisfy the standing wave condition.
Used
- Formula Substitution
Application:
- Use 2πr = nλ.
Final Logic:
- For n = 3, circumference = 3λ.
Orbit Number = Number of Wavelengths
10 Which is an incorrect statement regarding the quantisation rule and de Broglie's explanation?
�� Stable orbits require standing waves. �� Non-integral wavelengths cancel out. �� Only resonance survives.
For a stable orbit: 2πr = nλ Only integral numbers of wavelengths produce standing waves. Non-integral wavelengths lead to destructive interference and cannot persist. Therefore, option C is correct.
- �� Option A → Correct.
- �� Option B → Correct.
- �� Option D → Correct derivation of Bohr quantisation.
Used
- Wave Condition Analysis
Application:
- Apply standing wave requirement.
Final Logic:
- Non-integral wavelengths are not stable.
Whole Waves Stay, Fractional Waves Fade
11 During a transition from state n = 3 to n = 2, the energy of the emitted photon in a hydrogen atom is:
�� Hydrogen energy levels are quantized. �� Photon energy equals energy difference. �� Transition is from n = 3 to n = 2.
For hydrogen: En = −13.6/n² eV E3 = −13.6/9 eV E2 = −13.6/4 eV Photon energy emitted: hν = E3 − E2 = (−13.6/9) − (−13.6/4) = 13.6 × (1/4 − 1/9) eV Therefore, option B is correct.
- �� Option A → Uses incorrect energy dependence.
- �� Option C → Gives negative photon energy.
- �� Option D → Incorrect expression.
Used
- Substitution
Application:
- Apply Bohr energy formula directly.
Final Logic:
- hν = 13.6 × (1/4 − 1/9) eV.
Emission = Lower Orbit Term − Higher Orbit Term
12 In Bohr's model, the frequency of the emitted photon during a transition:
�� Photon frequency depends on energy difference. �� Orbit frequency and photon frequency are generally different. �� Agreement occurs only for large n.
Bohr's frequency condition states: hν = Ei − Ef Thus emitted frequency depends on the difference in energy levels and not directly on the electron's orbital frequency. Only for very large quantum numbers does correspondence approximately occur. Therefore, option C is correct.
- �� Option A → Not generally true.
- �� Option B → Not generally true.
- �� Option D → Energy levels determine frequency.
Used
- Conceptual Analysis
Application:
- Distinguish orbital frequency from photon frequency.
Final Logic:
- Photon frequency is governed by ΔE/h.
Photon Frequency = Energy Difference Frequency
13 The absorption spectrum of a material:
1. shows bright lines on a dark background.
2. contains dark lines corresponding to frequencies where photons have exactly the energy needed to excite an electron.
3. is independent of the atom's energy states.
4. forms a completely continuous dark band.
Choose correct:
�� Absorption removes specific wavelengths. �� Missing wavelengths appear dark. �� Energy matches atomic transitions.
When white light passes through a cooler gas, atoms absorb photons whose energies exactly match allowed electronic transitions. These missing wavelengths appear as dark lines in the spectrum. Hence statement 2 is correct.
- �� Option A → Describes emission spectrum.
- �� Option C → Absorption depends on energy levels.
- �� Option D → Absorption spectrum contains discrete dark lines.
Used
- Odd One Out
Application:
- Differentiate absorption from emission spectra.
Final Logic:
- Dark lines correspond to absorbed transition energies.
Absorption = Missing Lines
14 Choose the correct statements related to energy, frequency and transitions:
1. Ei − Ef = hν applies for emission.
2. Ei + hν = Ef applies for absorption, where nf > ni.
3. Bohr's model can accurately predict the relative intensities of the emitted frequencies.
4. Atomic energies are often expressed in electron volts rather than joules.
�� Emission obeys hν = Ei − Ef. �� Absorption obeys Ei + hν = Ef. �� Energy levels are commonly expressed in eV.
Statement 1 is correct. Statement 2 is correct. Statement 3 is incorrect because Bohr's model cannot explain spectral line intensities. Statement 4 is correct because atomic energies are commonly measured in electron volts. Therefore, statements (1), (2) and (4) are correct.
- �� Option A → Includes incorrect statement 3.
- �� Option B → Includes incorrect statement 3.
- �� Option D → Includes incorrect statement 3.
Used
- Elimination
Application:
- Identify the known limitation of Bohr's model.
Final Logic:
- Bohr explains frequencies but not intensities.
Bohr → Frequencies Yes, Intensities No
15 Choose the correct statements about the quantised orbit radius:
1. The radius is proportional to the square of the principal quantum number.
2. The smallest possible radius corresponds to n = 1.
3. The spacing between successive orbits (rₙ₊₁ − rₙ) is constant.
4. The radius expression includes the mass of the electron in the denominator.
�� rn ∝ n². �� Ground state has minimum radius. �� Orbit spacing is not uniform.
For hydrogen: rn = (ε₀ h² n²)/(π m e²) Therefore: Statement 1 is correct. Statement 2 is correct. Statement 3 is incorrect because orbit spacing increases with n. Statement 4 is correct. Thus, option A is correct.
- �� All include statement 3, which is false.
Used
- Formula Verification
Application:
- Use Bohr radius formula.
Final Logic:
- rn ∝ n² and contains m in denominator.
Radius Grows as n²
16 If the Bohr radius a₀ = 5.3 × 10⁻¹¹ m, what is the radius of the second excited state of a hydrogen atom?
�� Second excited state means n = 3. �� Radius varies as n². �� r₃ = 9a₀.
Second excited state: n = 3 r₃ = n²a₀ = 9 × 5.3 × 10⁻¹¹ = 4.77 × 10⁻¹⁰ m Therefore, option C is correct.
- �� Option A → Corresponds to n = 2.
- �� Option B → Incorrect value.
- �� Option D → Too large.
Used
- Substitution
Application:
- Apply rₙ = n²a₀.
Final Logic:
- r₃ = 9a₀ = 4.77 × 10⁻¹⁰ m.
Second Excited = n³? No, n = 3
17 Match List I (Energy expressions in Bohr orbit) with List II (Dependencies in terms of constants)
| List I | List II |
|---|---|
| 1. Total Energy E | a. −e²/(8πε₀r) |
| 2. Potential Energy U | b. −e²/(4πε₀r) |
| 3. Kinetic Energy K | c. e²/(8πε₀r) |
| 4. Radius r | d. ε₀h²n²/(πme²) |
�� E = K + U. �� K positive. �� U negative.
List I — List II 1. Total Energy E — a. −e²/(8πε₀r) 2. Potential Energy U — b. −e²/(4πε₀r) 3. Kinetic Energy K — c. e²/(8πε₀r) 4. Radius r — d. ε₀h²n²/(πme²) Thus option A is correct.
- �� They contain incorrect formula pairings.
Used
- Formula Matching
Application:
- Recall standard Bohr orbit expressions.
Final Logic:
- Only option A satisfies all relations.
U = −2K and E = −K
18 As the principal quantum number n increases, the absolute value of energy becomes _______, and the total energy E becomes progressively _______.
�� En = −13.6/n² eV. �� Magnitude decreases with n. �� Energy approaches zero.
As n increases: |En| = 13.6/n² decreases continuously. The energy becomes less negative and approaches zero. Hence option A is correct.
- �� Opposite trends are given.
Used
- Formula Analysis
Application:
- Use En = −13.6/n².
Final Logic:
- Higher n means weaker binding.
Higher n → Nearer Zero
19 The ground state of a hydrogen atom is defined such that:
�� Ground state corresponds to n = 1. �� Lowest energy state. �� Smallest orbit radius.
For hydrogen: E1 = −13.6 eV This is the most negative allowed energy and corresponds to the smallest orbit radius. Therefore, option B is correct.
- �� Option A → Electron is moving.
- �� Option C → Describes ionized state.
- �� Option D → Ground state does not radiate.
Used
- Definition Recall
Application:
- Identify properties of n = 1 state.
Final Logic:
- Ground state = lowest energy, smallest orbit.
Ground = n1 = −13.6 eV
20 Which is an incorrect statement regarding the higher energy states (excited states)?
�� Most atoms remain in ground state. �� Excited states require energy input. �� Energy levels converge at large n.
At room temperature, thermal energy is insufficient to place most hydrogen atoms in highly excited states. Most atoms remain in the ground state. Statements B, C and D are correct. Therefore, option A is incorrect.
- �� Option B → Correct; E∞ = 0 eV.
- �� Option C → Energy levels crowd together at large n.
- �� Option D → Hydrogen ionization energy is 13.6 eV.
Used
- Extreme Word Filter
Application:
- Check for unrealistic absolute claims.
Final Logic:
- Most hydrogen atoms are not automatically highly excited.
Room Temperature → Ground State Dominates
