CUET UG Physics Booster Test 2- Bohr Model Postulates
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QUESTION 1 OF 20
According to classical electromagnetic theory applied to atoms:
QUESTION 2 OF 20
Match List I with List II for a classical revolving electron:
| List I | List II |
|---|---|
| 1. Nature of force | a. Continuous energy decrease |
| 2. Source of acceleration | b. Coulomb's Law of force |
| 3. Electromagnetic theory consequence | c. Fall into nucleus |
| 4. End result | d. Change in velocity direction (circular motion) |
QUESTION 3 OF 20
In a classical atom model with an inward spiralling electron:
QUESTION 4 OF 20
Which is an incorrect statement about the radiation collapse of the classical atom?
QUESTION 5 OF 20
Choose the correct statements about continuous frequency emission:
1. Revolving electrons emit electromagnetic waves with a frequency equal to their frequency of revolution.
2. As the orbit shrinks, the frequency of revolution changes.
3. This results in the emission of a continuous spectrum.
4. This classical prediction perfectly matched experimental observations.
QUESTION 6 OF 20
The classical model predicted a _______ spectrum, while the actually observed spectrum of atomic hydrogen is a _______ spectrum.
QUESTION 7 OF 20
Choose the correct statements about Bohr's stable orbits:
1. They are a radical departure from established principles of classical electromagnetism.
2. They are governed exclusively by gravitational forces.
3. They resolve the classical difficulty of the inward spiral.
4. Electrons in these orbits do not emit radiant energy.
QUESTION 8 OF 20
If an atom is in a stationary state n, the energy associated with it represents:
QUESTION 9 OF 20
What is the angular momentum of an electron in the n = 2 state of a hydrogen atom?
(h = 6.63 × 10⁻³⁴ J s, π = 3.14)
QUESTION 10 OF 20
Which is an incorrect statement about the quantisation rule?
QUESTION 11 OF 20
In an atomic gas at low pressure passing an electric current, when an electron falls back to a state of lower energy:
QUESTION 12 OF 20
Transition from higher to lower energy causes _______, whereas transition from lower to higher energy requires _______.
QUESTION 13 OF 20
If an electron transitions from orbit ni to nf (where ni > nf), the energy of the emitted photon is proportional to:
QUESTION 14 OF 20
Choose the correct statements regarding the relationship hν = Ei − Ef:
1. h is the Planck's constant.
2. The frequency ν emitted depends directly on the energy difference.
3. This incorporates Einstein and Planck's quantum concepts into the atomic theory.
4. The frequency of the emitted photon equals the electron's frequency of revolution.
QUESTION 15 OF 20
Match List I with List II for Bohr radius rn dependencies:
| List I | List II |
|---|---|
| 1. Mass of electron (m) | a. Directly proportional to n² |
| 2. Principal quantum number (n) | b. Inversely proportional to m |
| 3. Planck constant (h) | c. Directly proportional to h² |
| 4. Permittivity (ε₀) | d. Directly proportional to ε₀ |
QUESTION 16 OF 20
The Bohr radius a₀ of the lowest energy state:
QUESTION 17 OF 20
Choose the correct statements regarding total energy expressions:
1. Total energy is the sum of kinetic and electrostatic potential energy.
2. Total energy E = −e²/(8πε₀r).
3. The potential energy is positive while kinetic is negative.
4. Kinetic energy K = e²/(8πε₀r).
QUESTION 18 OF 20
If the total energy E of an electron in an atom were positive:
QUESTION 19 OF 20
What is the energy required to excite an electron in a hydrogen atom from its ground state (n = 1) to its first excited state (n = 2)?
(Ground state energy = −13.6 eV)
QUESTION 20 OF 20
Which is an incorrect statement about atomic excitation?
Test Complete!
Answer Review
1 According to classical electromagnetic theory applied to atoms:
�� Accelerating charges emit electromagnetic radiation. �� Circular motion involves acceleration. �� This led to the instability problem of Rutherford's atom.
According to classical electromagnetic theory, any accelerating charged particle continuously emits electromagnetic radiation. Since an electron moving around the nucleus undergoes centripetal acceleration, it should continuously radiate energy. Therefore, option A is correct.
- �� Option B → Circular motion always involves centripetal acceleration.
- �� Option C → Classical theory predicts emission, not continuous absorption.
- �� Option D → The acceleration is centripetal (towards the centre), not tangential.
Used
- Elimination
Application:
- Reject statements inconsistent with circular motion and electromagnetic theory.
Final Logic:
- Accelerating charges continuously emit electromagnetic radiation.
Accelerate → Radiate
2 Match List I with List II for a classical revolving electron:
| List I | List II |
|---|---|
| 1. Nature of force | a. Continuous energy decrease |
| 2. Source of acceleration | b. Coulomb's Law of force |
| 3. Electromagnetic theory consequence | c. Fall into nucleus |
| 4. End result | d. Change in velocity direction (circular motion) |
�� Coulomb force provides attraction. �� Circular motion causes acceleration. �� Radiation causes energy loss.
1 → b : Force between nucleus and electron is Coulomb force. 2 → d : Circular motion changes velocity direction, causing acceleration. 3 → a : Radiation leads to continuous energy decrease. 4 → c : Energy loss causes the electron to fall into the nucleus. Thus, option A is correct.
- �� Option B → Incorrect matching of all major concepts.
- �� Option C → Acceleration source matched incorrectly.
- �� Option D → Nature of force and acceleration mismatched.
Used
- Option Grouping
Application:
- Match each concept with its physical consequence.
Final Logic:
- Only option A correctly links all classical predictions.
Coulomb → Acceleration → Radiation → Collapse
3 In a classical atom model with an inward spiralling electron:
�� Orbit continuously shrinks. �� Orbital frequency changes continuously. �� Emitted frequency also changes continuously.
As the electron loses energy, its orbit shrinks. Consequently, its angular velocity and frequency of revolution continuously change. Since classical theory assumes emitted radiation frequency equals orbital frequency, the emitted light frequency also changes continuously. Therefore, option A is correct.
- �� Option B → Angular velocity does not remain constant.
- �� Option C → Revolution frequency changes continuously.
- �� Option D → Energy loss directly affects orbital motion.
Used
- Contextual/Tonal Matching
Application:
- Follow the consequences of continuous energy loss.
Final Logic:
- Changing orbit produces continuously changing frequency.
Shrinking Orbit → Changing Frequency
4 Which is an incorrect statement about the radiation collapse of the classical atom?
�� Classical model predicts instability. �� Electron continuously loses energy. �� Matter should collapse according to the model.
The major failure of Rutherford's model was its inability to explain atomic stability. Classical theory predicts that electrons radiate continuously and spiral into the nucleus. Therefore, option C is correct.
- �� Option A → Correct consequence of energy loss.
- �� Option B → Correct classical prediction.
- �� Option D → Correct description of Rutherford's model.
Used
- Odd One Out
Application:
- Identify the statement contradicting the known failure of the model.
Final Logic:
- The classical model fails to explain stability.
Classical Atom = Unstable Atom
5 Choose the correct statements about continuous frequency emission:
1. Revolving electrons emit electromagnetic waves with a frequency equal to their frequency of revolution.
2. As the orbit shrinks, the frequency of revolution changes.
3. This results in the emission of a continuous spectrum.
4. This classical prediction perfectly matched experimental observations.
�� Orbital frequency changes continuously. �� Emitted frequency changes continuously. �� Continuous spectrum is predicted.
Statements 1, 2 and 3 are correct. Classical theory predicts that emitted radiation has the same frequency as electron revolution. Since the revolution frequency changes continuously as the orbit shrinks, a continuous spectrum is expected. Statement 4 is incorrect because experiments showed line spectra.
- �� Option B → Includes incorrect statement 4.
- �� Option C → Includes incorrect statement 4.
- �� Option D → Includes incorrect statement 4.
Used
- Elimination
Application:
- Remove the statement contradicting experimental evidence.
Final Logic:
- Continuous spectrum prediction disagreed with observation.
Changing Orbit → Continuous Spectrum
6 The classical model predicted a _______ spectrum, while the actually observed spectrum of atomic hydrogen is a _______ spectrum.
�� Classical theory predicts continuous frequencies. �� Hydrogen shows discrete lines. �� This motivated Bohr's theory.
Classical theory predicts a continuous spectrum because orbital frequency changes continuously. Experimentally, hydrogen exhibits a line spectrum consisting of discrete wavelengths. Therefore, option B is correct.
- �� Option A → Reversed order.
- �� Option C → Observed hydrogen spectrum is not continuous.
- �� Option D → Classical prediction is not line spectrum.
Used
- Odd One Out
Application:
- Compare theoretical prediction with experimental observation.
Final Logic:
- Predicted continuous, observed line spectrum.
Classical = Continuous, Hydrogen = Line
7 Choose the correct statements about Bohr's stable orbits:
1. They are a radical departure from established principles of classical electromagnetism.
2. They are governed exclusively by gravitational forces.
3. They resolve the classical difficulty of the inward spiral.
4. Electrons in these orbits do not emit radiant energy.
�� Stable orbits are non-radiating. �� They contradict classical expectations. �� They prevent atomic collapse.
Statements 1, 3 and 4 are correct. Bohr introduced stationary orbits in which electrons do not radiate energy. This was a major departure from classical theory and solved the instability problem. Statement 4 is incorrect because electrostatic attraction governs atomic motion.
- �� Option A → Includes statement 2.
- �� Option B → Includes statement 2.
- �� Option D → Includes statement 2.
Used
- Elimination
Application:
- Remove the statement involving gravitational forces.
Final Logic:
- Atomic orbits are governed by electrostatic attraction.
Bohr Orbit = Stable & Non-Radiating
8 If an atom is in a stationary state n, the energy associated with it represents:
�� Energy is quantized. �� Depends on n². �� Negative sign indicates binding.
For hydrogen: En = −13.6/n² eV This gives the energy of the nth stationary state. Therefore, option A is correct.
- �� Option B → Wrong sign and dependence.
- �� Option C → Incorrect n² dependence.
- �� Option D → Missing negative sign.
Used
- Formula Recall
Application:
- Recall Bohr energy expression.
Final Logic:
- En = −13.6/n² eV.
Energy → −13.6/n²
9 What is the angular momentum of an electron in the n = 2 state of a hydrogen atom?
(h = 6.63 × 10⁻³⁴ J s, π = 3.14)
�� Use Bohr quantization rule. �� L = nh/2π. �� Substitute n = 2.
L = nh/(2π) L = (2 × 6.63 × 10⁻³⁴)/(2 × 3.14) L = 13.26 × 10⁻³⁴ / 6.28 L = 2.11 × 10⁻³⁴ kg m²/s Therefore, option B is correct.
- �� Option A → Corresponds approximately to n = 1.
- �� Option C → Twice the correct value.
- �� Option D → Incorrect calculation.
Used
- Substitution
Application:
- Apply L = nh/2π.
Final Logic:
- Substitution gives 2.11 × 10⁻³⁴ kg m²/s.
n = 2 ⇒ L = 2h/2π
10 Which is an incorrect statement about the quantisation rule?
�� Quantization was introduced as a postulate. �� Classical mechanics cannot derive it. �� De Broglie later explained it.
Bohr introduced angular momentum quantization as a postulate. It was not derived from classical mechanics. Later, de Broglie's matter-wave theory provided a physical explanation. Therefore, option C is correct.
- �� Option A → Correct statement.
- �� Option B → Correct quantization condition.
- �� Option D → Correct implication of quantization.
Used
- Odd One Out
Application:
- Identify the statement inconsistent with the history of Bohr's theory.
Final Logic:
- Quantization was postulated, not classically derived.
Bohr Postulated, de Broglie Explained
11 In an atomic gas at low pressure passing an electric current, when an electron falls back to a state of lower energy:
�� Electrons transition between discrete energy levels. �� Downward transition emits a photon. �� Specific energy differences produce line spectra.
According to Bohr's third postulate, when an electron moves from a higher energy state to a lower energy state, it emits a photon whose energy equals the energy difference between the two states. hν = Ei − Ef Since only certain energy levels are allowed, only specific wavelengths are emitted, producing an emission line spectrum. Therefore, option A is correct.
- �� Option B → Absorption occurs during upward transitions.
- �� Option C → Atomic gases produce line spectra, not continuous spectra.
- �� Option D → Electrons do not lose mass during emission.
Used
- Contextual/Tonal Matching
Application:
- Relate electron transitions to emission spectra.
Final Logic:
- Downward transition produces discrete photon emission.
Fall Down → Photon Out
12 Transition from higher to lower energy causes _______, whereas transition from lower to higher energy requires _______.
�� Downward transition releases energy. �� Upward transition requires energy. �� Energy exchange occurs through photons.
When an electron moves from a higher energy state to a lower energy state, energy is released as a photon (emission). When an electron moves from a lower energy state to a higher energy state, energy must be supplied through photon absorption. Therefore, option B is correct.
- �� Option A → Reverses the processes.
- �� Option C → Ionisation is not required for ordinary transitions.
- �� Option D → Incorrect description of energy transfer.
Used
- Odd One Out
Application:
- Identify the correct sequence of energy release and gain.
Final Logic:
- Higher → Lower = Emission; Lower → Higher = Absorption.
Down = Emit, Up = Absorb
13 If an electron transitions from orbit ni to nf (where ni > nf), the energy of the emitted photon is proportional to:
�� Hydrogen energy levels vary as 1/n². �� Photon energy equals level difference. �� Final lower orbit has larger energy magnitude.
For hydrogen: En = −13.6/n² eV Therefore, hν = Ei − Ef = [−13.6/ni²] − [−13.6/nf²] = 13.6[(1/nf²) − (1/ni²)] Hence photon energy is proportional to: (1/nf² − 1/ni²) Therefore, option A is correct.
- �� Option B → Gives the negative of the required expression.
- �� Option C → Incorrect dependence.
- �� Option D → Negative quantity for emission.
Used
- Substitution
Application:
- Substitute Bohr energy expression into hν = Ei − Ef.
Final Logic:
- Photon energy depends on the difference of inverse squares.
Emission = Lower Level Term − Higher Level Term
14 Choose the correct statements regarding the relationship hν = Ei − Ef:
1. h is the Planck's constant.
2. The frequency ν emitted depends directly on the energy difference.
3. This incorporates Einstein and Planck's quantum concepts into the atomic theory.
4. The frequency of the emitted photon equals the electron's frequency of revolution.
�� Photon energy equals energy difference. �� Frequency depends on ΔE. �� Bohr used quantum concepts.
Statement 1 is correct because h is Planck's constant. Statement 2 is correct since: ν = (Ei − Ef)/h Statement 3 is correct because Bohr incorporated Planck's quantization and Einstein's photon concept. Statement 4 is incorrect because emitted photon frequency is determined by energy difference, not electron revolution frequency.
- �� Option A → Includes incorrect statement 4.
- �� Option C → Includes incorrect statement 4.
- �� Option D → Includes incorrect statement 4.
Used
- Elimination
Application:
- Remove the statement based on classical frequency prediction.
Final Logic:
- Photon frequency depends on energy difference, not orbital frequency.
Photon Frequency = ΔE/h
15 Match List I with List II for Bohr radius rn dependencies:
| List I | List II |
|---|---|
| 1. Mass of electron (m) | a. Directly proportional to n² |
| 2. Principal quantum number (n) | b. Inversely proportional to m |
| 3. Planck constant (h) | c. Directly proportional to h² |
| 4. Permittivity (ε₀) | d. Directly proportional to ε₀ |
�� Radius depends on n². �� Radius is inversely proportional to mass. �� Radius depends on h² and ε₀.
Bohr radius relation: rn = (ε₀n²h²)/(πme²) Therefore: 1 → b 2 → a 3 → c 4 → d Thus option A is correct.
- �� Option B → Incorrect matching.
- �� Option C → Incorrect matching.
- �� Option D → Incorrect matching.
Used
- Option Grouping
Application:
- Match each parameter using the Bohr radius formula.
Final Logic:
- Only option A satisfies all dependencies.
Radius ∝ ε₀h²n²/m
16 The Bohr radius a₀ of the lowest energy state:
�� Ground state has n = 1. �� Bohr radius belongs to ground state. �� Value is 5.3 × 10⁻¹¹ m.
The Bohr radius a₀ is the radius of the first orbit (ground state). a₀ = 5.3 × 10⁻¹¹ m Therefore, option C is correct.
- �� Option A → n = 2 is first excited state.
- �� Option B → Incorrect value (one order larger).
- �� Option D → Not a maximum distance.
Used
- Formula Recall
Application:
- Recall definition of Bohr radius.
Final Logic:
- Bohr radius corresponds to n = 1.
a₀ = First Orbit
17 Choose the correct statements regarding total energy expressions:
1. Total energy is the sum of kinetic and electrostatic potential energy.
2. Total energy E = −e²/(8πε₀r).
3. The potential energy is positive while kinetic is negative.
4. Kinetic energy K = e²/(8πε₀r).
�� E = K + U. �� K is positive. �� U is negative.
Statement 1 is correct because total energy equals kinetic plus potential energy. Statement 2 is correct: E = −e²/(8πε₀r) Statement 4 is correct: K = e²/(8πε₀r) Statement 3 is incorrect because kinetic energy is positive and potential energy is negative.
- �� Option B → Includes incorrect statement 3.
- �� Option C → Includes incorrect statement 3.
- �� Option D → Includes incorrect statement 3.
Used
- Elimination
Application:
- Identify the sign convention error.
Final Logic:
- K > 0 and U < 0.
K Positive, U Negative
18 If the total energy E of an electron in an atom were positive:
�� Positive energy means unbound state. �� Electron can escape. �� Closed orbit is impossible.
A bound electron has negative total energy. If total energy becomes zero or positive, the electron is no longer bound to the nucleus and cannot remain in a closed orbit. Therefore, option A is correct.
- �� Option B → Positive energy does not imply spiralling inward.
- �� Option C → Positive energy means less bound, not more.
- �� Option D → Not the defining consequence.
Used
- Definition Recall
Application:
- Interpret the physical meaning of positive energy.
Final Logic:
- Positive total energy corresponds to an unbound electron.
Positive E = Escape
19 What is the energy required to excite an electron in a hydrogen atom from its ground state (n = 1) to its first excited state (n = 2)?
(Ground state energy = −13.6 eV)
�� E₁ = −13.6 eV. �� E₂ = −3.4 eV. �� Excitation energy = difference.
For hydrogen: E₂ = −13.6/2² = −3.4 eV Required energy: ΔE = E₂ − E₁ = (−3.4) − (−13.6) = 10.2 eV Therefore, option B is correct.
- �� Option A → Equals magnitude of E₂.
- �� Option C → Corresponds to n = 3 excitation.
- �� Option D → Ionization energy from ground state.
Used
- Substitution
Application:
- Use Bohr energy formula.
Final Logic:
- 10.2 eV is needed for n = 1 → n = 2.
1 → 2 = 10.2 eV
20 Which is an incorrect statement about atomic excitation?
�� Higher excited states are less tightly bound. �� Ionization energy decreases with n. �� Excited electrons are easier to remove.
As the electron moves to higher energy levels, its total energy approaches zero. Therefore, less energy is required to remove it completely from the atom. For example: E₃ = −13.6/9 = −1.51 eV Only 1.51 eV is needed to ionize from n = 3. Thus option D is correct.
- �� Option A → Correct; hydrogen ionization energy is 13.6 eV.
- �� Option B → Correct description of de-excitation.
- �� Option C → Correct because E₃ − E₁ = 12.09 eV.
Used
- Extreme Word Filter
Application:
- Check how ionization energy changes with increasing excitation.
Final Logic:
- Higher excitation means lower ionization energy.
Higher n → Easier Ionization
