CUET UG Chemistry Booster Test - 1 Classification and Basics
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QUESTION 1 OF 20
Alcohol structural properties:
1. Contain one or more hydroxyl groups
2. The -OH group is directly attached to a carbon of an aromatic system
3. Formed by replacing a hydrogen atom in an aliphatic hydrocarbon
4. Examples include CH₃OH
QUESTION 2 OF 20
Which of the following compounds accurately represents the fundamental definition of a phenol?
QUESTION 3 OF 20
Match List I with List II.
| List I | List II |
|---|---|
| 1. CH₃OCH₃ | a. Methyl phenyl ether |
| 2. C₂H₅OC₂H₅ | b. Diethyl ether |
| 3. C₆H₅OCH₃ | c. Ethyl phenyl ether |
| 4. C₆H₅OCH₂CH₃ | d. Dimethyl ether |
QUESTION 4 OF 20
The bond angle (C-O-C) in ethers is slightly greater than the tetrahedral angle due to the repulsive interaction between the two bulky groups. The value of this angle in methoxymethane is:
QUESTION 5 OF 20
Arrange the following primary alcohols in decreasing order of their carbon chain length:
1. Methanol
2. Butan-1-ol
3. Propan-1-ol
4. Ethanol
QUESTION 6 OF 20
IUPAC name of the secondary alcohol derived from butane is:
QUESTION 7 OF 20
QUESTION 8 OF 20
QUESTION 9 OF 20
Identify the classification type of the compound where an -OH group is attached to a -CH(CH₃)- group which is directly attached to a benzene ring.
QUESTION 10 OF 20
In vinylic alcohols, the hybridization of the carbon atom directly bonded to the hydroxyl oxygen is:
QUESTION 11 OF 20
IUPAC name of the monohydric alcohol containing three carbon atoms with the -OH on the second carbon is:
QUESTION 12 OF 20
Match List I with List II.
| List I | List II |
|---|---|
| 1. Methanol | a. Dihydric |
| 2. Ethylene glycol | b. Trihydric |
| 3. Glycerol | c. Monohydric |
| 4. Resorcinol | d. Polyhydric |
QUESTION 13 OF 20
Trihydric alcohol properties:
1. Propane-1,2,3-triol is an example
2. Contain three -OH groups
3. Retain the 'e' of alkane in IUPAC naming
4. Also called catechols
QUESTION 14 OF 20
The IUPAC naming convention for polyhydric alcohols retains the 'e' of the parent alkane name. Which of the following is correct for a dihydric alcohol of ethane?
QUESTION 15 OF 20
IUPAC name of the monohydric phenol with a methyl group at the para position is:
QUESTION 16 OF 20
Arrange the following dihydric phenols in decreasing order of the positional numbers of their hydroxyl groups (e.g., 1,4 > 1,3 > 1,2):
1. Catechol
2. Resorcinol
3. Hydroquinone
4. Phenol
QUESTION 17 OF 20
Identify the classification type of a compound having a benzene ring directly attached to three -OH groups.
QUESTION 18 OF 20
When phenol is substituted with a methyl group at the ortho position, the common name of the resulting compound is:
QUESTION 19 OF 20
Symmetrical ether properties:
1. The alkyl or aryl groups attached to the oxygen are identical
2. Diethyl ether is an example
3. C₂H₅OCH₃ is an example
4. Also known as simple ethers
QUESTION 20 OF 20
IUPAC name of the unsymmetrical ether CH₃OCH₂CH₂CH₃ is:
Test Complete!
Answer Review
1 Alcohol structural properties:
1. Contain one or more hydroxyl groups
2. The -OH group is directly attached to a carbon of an aromatic system
3. Formed by replacing a hydrogen atom in an aliphatic hydrocarbon
4. Examples include CH₃OH
�� Alcohols contain hydroxyl groups. �� Alcohols are derived from aliphatic hydrocarbons. �� Methanol is the simplest alcohol.
Statement 1 is correct because alcohols contain one or more hydroxyl (-OH) groups. Statement 2 is incorrect because an -OH group directly attached to an aromatic ring forms a phenol, not an alcohol. Statement 3 is correct because alcohols are formed by replacing a hydrogen atom in an aliphatic hydrocarbon with an -OH group. Statement 4 is correct because CH₃OH (methanol) is an alcohol. Therefore, option B is correct.
- �� Option A → Includes statement 2, which is incorrect.
- �� Option C → Includes statement 2 and omits statement 1.
- �� Option D → Includes statement 2, which is incorrect.
Used
- Elimination
Application:
- Check each statement against the NCERT definition of alcohols.
Final Logic:
- Statements 1, 3 and 4 are correct; statement 2 is incorrect.
Alcohol = Aliphatic + OH
2 Which of the following compounds accurately represents the fundamental definition of a phenol?
�� Phenol contains a benzene ring. �� OH group is directly attached to the ring. �� Formula of phenol is C₆H₅OH.
Phenol is defined as a compound in which the hydroxyl group is directly attached to an aromatic ring. C₆H₅OH satisfies this condition and is therefore phenol. Option A is benzyl alcohol, option C is methanol, and option D is dimethyl ether.
- �� Option A → Benzyl alcohol; OH is attached to a side-chain carbon.
- �� Option C → Methanol is an alcohol, not a phenol.
- �� Option D → Dimethyl ether is an ether.
Used
- Odd One Out
Application:
- Identify the structure with OH directly attached to a benzene ring.
Final Logic:
- Phenol = C₆H₅OH.
Phenol = Phenyl + OH
3 Match List I with List II.
| List I | List II |
|---|---|
| 1. CH₃OCH₃ | a. Methyl phenyl ether |
| 2. C₂H₅OC₂H₅ | b. Diethyl ether |
| 3. C₆H₅OCH₃ | c. Ethyl phenyl ether |
| 4. C₆H₅OCH₂CH₃ | d. Dimethyl ether |
�� Common names depend on groups attached to oxygen. �� Same alkyl groups form simple ethers. �� Aromatic ethers contain phenyl groups.
1 → d : CH₃OCH₃ is dimethyl ether. 2 → b : C₂H₅OC₂H₅ is diethyl ether. 3 → a : C₆H₅OCH₃ is methyl phenyl ether (anisole). 4 → c : C₆H₅OCH₂CH₃ is ethyl phenyl ether. Therefore, option A is correct.
- �� Option B → CH₃OCH₃ and C₆H₅OCH₂CH₃ are incorrectly matched.
- �� Option C → Diethyl ether and methyl phenyl ether are interchanged.
- �� Option D → CH₃OCH₃ and C₂H₅OC₂H₅ are incorrectly matched.
Used
- Option Grouping
Application:
- Match ether structures with their standard common names.
Final Logic:
- Dimethyl, Diethyl, Methyl Phenyl and Ethyl Phenyl correspond respectively.
Di-Me, Di-Et, Anisole, Phenetole
4 The bond angle (C-O-C) in ethers is slightly greater than the tetrahedral angle due to the repulsive interaction between the two bulky groups. The value of this angle in methoxymethane is:
�� Ether bond angle exceeds tetrahedral angle. �� Lone pair and bulky group repulsions affect geometry. �� Methoxymethane has a bond angle of 111.7°.
According to NCERT, the C–O–C bond angle in methoxymethane is approximately 111.7°. This is slightly greater than the tetrahedral angle because of repulsion between the bulky alkyl groups attached to oxygen. Therefore, option C is correct.
- �� Option A → Not the reported NCERT value.
- �� Option B → Approximately tetrahedral but not the actual ether angle.
- �� Option D → Much larger than the observed value.
Used
- Memory-Based Elimination
Application:
- Recall the NCERT structural data for methoxymethane.
Final Logic:
- Methoxymethane has a C–O–C bond angle of 111.7°.
Ether Angle ≈ 112°
5 Arrange the following primary alcohols in decreasing order of their carbon chain length:
1. Methanol
2. Butan-1-ol
3. Propan-1-ol
4. Ethanol
�� Carbon chain length decreases from four to one carbon. �� Butanol has the longest chain. �� Methanol has the shortest chain.
Butan-1-ol contains four carbon atoms, propan-1-ol contains three, ethanol contains two and methanol contains one. Therefore, the decreasing order of carbon chain length is Butan-1-ol > Propan-1-ol > Ethanol > Methanol.
- �� Option B → Gives increasing order instead of decreasing order.
- �� Option C → Ethanol and propan-1-ol are incorrectly arranged.
- �� Option D → Butan-1-ol is not placed first.
Used
- Option Grouping
Application:
- Count carbon atoms in each alcohol.
Final Logic:
- 4C > 3C > 2C > 1C.
But > Prop > Eth > Meth
6 IUPAC name of the secondary alcohol derived from butane is:
�� Secondary alcohol has OH on a secondary carbon. �� Butane gives butan-2-ol as the secondary isomer. �� OH-bearing carbon is attached to two carbons.
In butan-2-ol, the hydroxyl group is attached to carbon-2, which is bonded to two other carbon atoms. Hence it is a secondary alcohol. Therefore, option B is correct.
- �� Option A → Primary alcohol.
- �� Option C → Branched primary alcohol.
- �� Option D → Tertiary alcohol.
Used
- Substitution
Application:
- Locate the hydroxyl group and determine the carbon type.
Final Logic:
- OH on secondary carbon = Butan-2-ol.
2-ol = Secondary
7
�� Tertiary alcohols contain C(sp³)-OH bonds. �� OH-bearing carbon is attached to three carbons. �� Classification depends on the carbon attached to OH.
The passage states that primary, secondary and tertiary alcohols contain C(sp³)-OH bonds. In a tertiary alcohol, the carbon bearing the hydroxyl group is attached to three other carbon atoms. Hence option B is correct.
- �� Option A → Describes vinylic systems.
- �� Option C → OH directly attached to a double-bond carbon is not a tertiary alcohol.
- �� Option D → Describes phenolic structures.
Used
- Contextual/Tonal Matching
Application:
- Use the classification information provided in the passage.
Final Logic:
- Tertiary alcohol = OH-bearing sp³ carbon attached to three carbons.
Tertiary = Three Carbon Neighbours
8
�� Allylic alcohols contain an sp³ carbon. �� The carbon is adjacent to a double bond. �� They may be primary, secondary or tertiary.
The passage clearly states that in allylic alcohols, the hydroxyl group is attached to an sp³ hybridized carbon adjacent to a carbon-carbon double bond. Therefore, option C is correct.
- �� Option A → Allylic alcohols may be primary, secondary or tertiary.
- �� Option B → The OH-bearing carbon is sp³, not sp².
- �� Option D → Allylic alcohols are not aromatic alcohols.
Used
- Contextual/Tonal Matching
Application:
- Directly identify the definition given in the passage.
Final Logic:
- Allylic alcohol = sp³ carbon adjacent to C=C.
Ally = Adjacent to Alkene
9 Identify the classification type of the compound where an -OH group is attached to a -CH(CH₃)- group which is directly attached to a benzene ring.
�� OH-bearing carbon is adjacent to a benzene ring. �� That carbon is attached to two carbons. �� Therefore it is secondary benzylic.
The carbon bearing the hydroxyl group is benzylic because it is directly attached to a benzene ring. It is secondary because that carbon is attached to two carbon groups. Hence the compound is a secondary benzylic alcohol.
- �� Option A → OH-bearing carbon is not attached to only one carbon.
- �� Option C → OH-bearing carbon is not attached to three carbons.
- �� Option D → No carbon-carbon double bond carbon bears the OH group.
Used
- Option Grouping
Application:
- Determine both benzylic position and degree of substitution.
Final Logic:
- Benzylic + two carbon attachments = Secondary benzylic alcohol.
Benzylic + Two = Secondary
10 In vinylic alcohols, the hybridization of the carbon atom directly bonded to the hydroxyl oxygen is:
�� Vinylic carbon participates in a double bond. �� Double-bond carbons are sp² hybridized. �� OH is directly attached to that carbon.
In a vinylic alcohol, the hydroxyl group is directly attached to a carbon atom involved in a carbon-carbon double bond. Such carbons are sp² hybridized. Therefore, option D is correct.
- �� Option A → Represents saturated tetrahedral carbons.
- �� Option B → Not applicable to vinylic carbon atoms.
- �� Option C → Represents triple-bond carbons.
Used
- Elimination
Application:
- Determine hybridization from the presence of a carbon-carbon double bond.
Final Logic:
- Vinylic carbon = sp² hybridization.
Vinyl = Double Bond = sp²
11 IUPAC name of the monohydric alcohol containing three carbon atoms with the -OH on the second carbon is:
�� The parent chain contains three carbon atoms. �� The hydroxyl group is on carbon 2. �� It is a secondary alcohol.
A three-carbon alcohol is derived from propane. Since the hydroxyl group is attached to carbon 2, the correct IUPAC name is propan-2-ol. Therefore, option B is correct.
- �� Option A → Hydroxyl group is attached to carbon 1.
- �� Option C → Contains a double bond and is not derived from propane.
- �� Option D → Contains four carbon atoms.
Used
- Substitution
Application:
- Identify the parent chain and locate the hydroxyl group.
Final Logic:
- Three carbons + OH on carbon 2 = Propan-2-ol.
3C + OH at 2 = Propan-2-ol
12 Match List I with List II.
| List I | List II |
|---|---|
| 1. Methanol | a. Dihydric |
| 2. Ethylene glycol | b. Trihydric |
| 3. Glycerol | c. Monohydric |
| 4. Resorcinol | d. Polyhydric |
�� Methanol contains one hydroxyl group. �� Ethylene glycol and resorcinol contain two hydroxyl groups. �� Glycerol contains three hydroxyl groups.
1 → c : Methanol contains one hydroxyl group and is monohydric. 2 → a : Ethylene glycol contains two hydroxyl groups and is dihydric. 3 → b : Glycerol contains three hydroxyl groups and is trihydric. 4 → a : Resorcinol is benzene-1,3-diol and is dihydric. Therefore, option D is correct.
- �� Option A → Incorrectly classifies methanol and resorcinol.
- �� Option B → Incorrectly classifies methanol and glycerol.
- �� Option C → Interchanges dihydric and trihydric classifications.
Used
- Option Grouping
Application:
- Count the number of hydroxyl groups present in each compound.
Final Logic:
- 1 OH = Monohydric, 2 OH = Dihydric, 3 OH = Trihydric.
Meth-1, Glycol-2, Glycerol-3
13 Trihydric alcohol properties:
1. Propane-1,2,3-triol is an example
2. Contain three -OH groups
3. Retain the 'e' of alkane in IUPAC naming
4. Also called catechols
�� Trihydric alcohols contain three hydroxyl groups. �� Glycerol is a common example. �� The parent alkane name retains the 'e'.
Statement 1 is correct because propane-1,2,3-triol (glycerol) is a trihydric alcohol. Statement 2 is correct because trihydric alcohols contain three hydroxyl groups. Statement 3 is correct because NCERT nomenclature retains the terminal 'e' of the alkane name in polyhydric alcohols. Statement 4 is incorrect because catechol is a dihydric phenol, not a trihydric alcohol. Therefore, option C is correct.
- �� Option A → Includes statement 4, which is incorrect.
- �� Option B → Includes statement 4, which is incorrect.
- �� Option D → Includes statement 4 and omits statement 2.
Used
- Elimination
Application:
- Verify each statement using definitions and nomenclature rules.
Final Logic:
- Statements 1, 2 and 3 are correct; statement 4 is incorrect.
Trihydric = Triol = 3 OH
14 The IUPAC naming convention for polyhydric alcohols retains the 'e' of the parent alkane name. Which of the following is correct for a dihydric alcohol of ethane?
�� Polyhydric alcohols retain the 'e' of the alkane. �� Two hydroxyl groups require the suffix "diol". �� Locants must be specified.
The correct IUPAC name is ethane-1,2-diol because the parent hydrocarbon is ethane and hydroxyl groups are present on carbons 1 and 2. NCERT specifies retention of the terminal 'e' in polyhydric alcohol nomenclature. Therefore, option B is correct.
- �� Option A → Incomplete IUPAC name without locants.
- �� Option C → Incorrect naming format.
- �� Option D → Common name, not the preferred IUPAC name.
Used
- Elimination
Application:
- Apply IUPAC nomenclature rules for polyhydric alcohols.
Final Logic:
- Ethane + OH on C-1 and C-2 = Ethane-1,2-diol.
Diol → Keep the "e"
15 IUPAC name of the monohydric phenol with a methyl group at the para position is:
�� Para position corresponds to carbon 4. �� Phenol is the parent compound. �� Methyl group occupies the para position.
In phenol, the hydroxyl-bearing carbon is numbered as carbon 1. The para position corresponds to carbon 4. Therefore, a methyl substituent at the para position gives the IUPAC name 4-methylphenol. Hence, option C is correct.
- �� Option A → Represents ortho-methylphenol.
- �� Option B → Represents meta-methylphenol.
- �� Option D → A dihydric phenol.
Used
- Substitution
Application:
- Determine the position of the methyl group relative to the hydroxyl group.
Final Logic:
- Para = Position 4.
Ortho-2, Meta-3, Para-4
16 Arrange the following dihydric phenols in decreasing order of the positional numbers of their hydroxyl groups (e.g., 1,4 > 1,3 > 1,2):
1. Catechol
2. Resorcinol
3. Hydroquinone
4. Phenol
�� Hydroquinone is benzene-1,4-diol. �� Resorcinol is benzene-1,3-diol. �� Catechol is benzene-1,2-diol. �� Phenol contains only one hydroxyl group.
3 → Hydroquinone corresponds to benzene-1,4-diol. 2 → Resorcinol corresponds to benzene-1,3-diol. 1 → Catechol corresponds to benzene-1,2-diol. 4 → Phenol contains only one hydroxyl group and therefore comes after the dihydric phenols when arranged according to the positional numbering sequence given. Therefore, the correct arrangement is: Hydroquinone > Resorcinol > Catechol > Phenol Hence, option A is correct.
- �� Option B → Gives the reverse order of the dihydric phenols.
- �� Option C → Places resorcinol before hydroquinone incorrectly.
- �� Option D → Interchanges catechol and resorcinol.
Used
- Option Grouping
Application:
- Recall the common names and corresponding IUPAC positions of the hydroxyl groups.
Final Logic:
- Hydroquinone (1,4) > Resorcinol (1,3) > Catechol (1,2) > Phenol.
Hydro-4, Res-3, Cate-2, Phenol-1
17 Identify the classification type of a compound having a benzene ring directly attached to three -OH groups.
�� Classification depends on hydroxyl count. �� Three hydroxyl groups indicate trihydric nature. �� All hydroxyl groups are attached to the aromatic ring.
A phenol containing three hydroxyl groups attached directly to a benzene ring is classified as a trihydric phenol. Therefore, option C is correct.
- �� Option A → Contains only one hydroxyl group.
- �� Option B → Contains two hydroxyl groups.
- �� Option D → Does not contain the phenolic hydroxyl arrangement.
Used
- Odd One Out
Application:
- Count the number of hydroxyl groups attached to the ring.
Final Logic:
- Three hydroxyl groups = Trihydric phenol.
Trihydric = Three OH
18 When phenol is substituted with a methyl group at the ortho position, the common name of the resulting compound is:
�� Cresols are methyl-substituted phenols. �� Ortho position corresponds to carbon 2. �� o-Cresol contains adjacent OH and CH₃ groups.
Phenol containing a methyl group at the ortho position is called o-cresol. The methyl group is adjacent to the hydroxyl group on the benzene ring. Therefore, option A is correct.
- �� Option B → Represents meta substitution.
- �� Option C → Represents para substitution.
- �� Option D → Anisole is methoxybenzene.
Used
- Memory-Based Elimination
Application:
- Recall the common names of methyl-substituted phenols.
Final Logic:
- Ortho methyl phenol = o-Cresol.
Ortho = o-Cresol
19 Symmetrical ether properties:
1. The alkyl or aryl groups attached to the oxygen are identical
2. Diethyl ether is an example
3. C₂H₅OCH₃ is an example
4. Also known as simple ethers
�� Symmetrical ethers contain identical groups. �� Diethyl ether is symmetrical. �� They are called simple ethers.
Statement 1 is correct because symmetrical ethers contain identical alkyl or aryl groups on both sides of oxygen. Statement 2 is correct because diethyl ether (C₂H₅OC₂H₅) is symmetrical. Statement 3 is incorrect because C₂H₅OCH₃ contains two different groups and is an unsymmetrical ether. Statement 4 is correct because symmetrical ethers are also called simple ethers. Therefore, option B is correct.
- �� Option A → Includes statement 3, which is incorrect.
- �� Option C → Includes statement 3 and omits statement 1.
- �� Option D → Includes statement 3, which is incorrect.
Used
- Elimination
Application:
- Compare the groups attached on both sides of oxygen.
Final Logic:
- Statements 1, 2 and 4 are correct; statement 3 is incorrect.
Same Groups = Simple Ether
20 IUPAC name of the unsymmetrical ether CH₃OCH₂CH₂CH₃ is:
�� Ethers are named as alkoxyalkanes. �� Propane is the longer carbon chain. �� Methoxy is the substituent.
The longer chain is propane and the smaller group attached through oxygen is methoxy. The methoxy group is attached to carbon 1 of propane. Therefore, the correct IUPAC name is 1-methoxypropane. Hence, option A is correct.
- �� Option B → Common name, not IUPAC name.
- �� Option C → Represents a different ether.
- �� Option D → Incorrect parent chain selection.
Used
- Substitution
Application:
- Select the longest carbon chain and treat the smaller group as an alkoxy substituent.
Final Logic:
- Propane parent chain + methoxy substituent = 1-Methoxypropane.
Long Chain = Parent
